水處理工藝，順酐是重要的有機(jī)化工基本原料，是消費(fèi)者僅次于醋酐和苯酐的第三大酸酐，順酐的主要用途是用于不飽和聚酯樹脂，另外，順酐還用于涂料、油墨、潤(rùn)滑油添加劑、農(nóng)用化學(xué)品、紙張施膠劑、紡織品整理劑、表面活性劑等方面，以順酐為原料還可以四氫呋喃、富馬酸、四氫苯酐等一系列重要的精細(xì)化工產(chǎn)品。
In water treatment process, maleic anhydride is an important basic raw material of organic chemical industry, and is the third largest anhydride after acetic anhydride and phthalic anhydride for consumers. The main purpose of maleic anhydride is to produce unsaturated polyester resin. In addition, maleic anhydride is also used in coatings, inks, lubricant additives, agricultural chemicals, paper sizing agents, textile finishing agents, surfactants and other aspects. With maleic anhydride as raw material, tetrahydrofuran, fumaric acid Tetrahydrophthalic anhydride and other important fine chemical products.
目前，順酐的是以苯和空氣為原料，順酐廢水處理系統(tǒng)采用催化劑經(jīng)固定氧化床氧化生成順酐物料氣，生成的順酐物料氣經(jīng)部分冷凝器冷凝后，氣體進(jìn)入到吸收塔被軟水吸收為濃度40%的順?biāo)崛芤海?0%的順?biāo)崛芤哼M(jìn)入到恒沸精餾段利用脫水劑脫去自由水和分子內(nèi)水，脫水劑為鄰二甲苯、二甲苯循環(huán)使用，脫水后的粗酐從粗酐罐中打入到連續(xù)恒沸塔中進(jìn)行精餾。
At present, the production of maleic anhydride is based on benzene and air. The wastewater treatment system of maleic anhydride production uses catalyst to oxidize in a fixed oxidation bed to generate maleic anhydride material gas. The generated maleic anhydride material gas is condensed in part of the condenser, and then enters the absorption tower to be absorbed by soft water into a 40% concentration of maleic acid solution. 40% of the maleic acid solution enters the azeotropic distillation section to remove free water and intramolecular water with dehydrator, which is o-xylene Xylene is recycled, and the dehydrated crude anhydride is pumped from the crude anhydride tank into the continuous azeotropic tower for distillation.
即可得到成品的順酐，上述方法在的過程中除了順酐之外，還會(huì)出一系列的副產(chǎn)物，隨著時(shí)間的加長(zhǎng)，這些副產(chǎn)物會(huì)造成設(shè)備堵塞，所以，在設(shè)備使用一段時(shí)間后需要用水進(jìn)行清洗，這樣容易產(chǎn)生廢水，且在恒沸精餾的過程中，恒沸塔和恒沸精餾釜內(nèi)會(huì)有部分殘留的順酐出現(xiàn)，如果將清洗后的廢水直接作為廢液進(jìn)行排放，既浪費(fèi)水源又污染環(huán)境。
The finished product of maleic anhydride can be obtained. In addition to maleic anhydride, the above method will also produce a series of by-products in the production process. With the extension of production time, these by-products will cause the production equipment to be blocked. Therefore, after the equipment is used for a period of time, it needs to be cleaned with water, which is easy to produce waste water. In the process of azeotropic distillation, there will be some residual maleic anhydride in the azeotropic tower and the azeotropic distillation kettle, If the waste water after cleaning is directly discharged as waste liquid, it will waste water and pollute the environment.
在現(xiàn)有的技術(shù)中，順酐的廢水大都采用現(xiàn)有的順酐廢水處理工藝進(jìn)行處理，也就是先將廢水進(jìn)行隔油處理，再加入強(qiáng)酸強(qiáng)堿進(jìn)行離心分離，之后再加入混凝劑進(jìn)行混凝處理，然后在進(jìn)行萃取，后再加入堿液進(jìn)行濃縮蒸餾，上述的順酐廢水處理工藝雖然實(shí)現(xiàn)了不同物質(zhì)的回收再利用，但是在處理的過程中，處理的過程較為復(fù)雜，處理的成本也較高，而且處理工藝的復(fù)雜
In the existing technology, the wastewater from maleic anhydride production is mostly treated by the existing maleic anhydride production wastewater treatment process, that is, the wastewater is first treated by oil separation, then added with strong acid and strong alkali for centrifugation, then added with coagulant for coagulation treatment, then extracted, and then added with alkali for concentration and distillation. Although the above maleic anhydride production wastewater treatment process realizes the recovery and reuse of different substances, But in the process of treatment, the treatment process is relatively complex, the treatment cost is also high, and the treatment process is complex
